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Surprisingly, in cold interstellar clouds, hydrogen cyanide, HCN, and the considerably more
energetic isomer of hydrogen cyanide, HNC (hydrogen isocyanide), have nearly equal abundance.
In a just in Astrophysical Journal Letters online published article
Mario B. Mendes et al. report on experiments that provide an explanation for this
phenomenon. These experiments have been performed by the group
"Molecular quantum dynamics and stored ion beams"
around Andreas Wolf
with the ion storage ring at the Max Planck Institute for Nuclear Physics in Heidelberg.
Please read more in the article ... >
Detailed information in the press release of the MPIK
Even after 35 years of activity and despite enormous advances in computers and experimental methods, the spectrum of the smallest triatomic molecular system, the H3+ ion, at higher excitations has remained an enigma neither fully accessed experimentally nor fully elucidated theoretically.
In a just in Physical Review Letters published article M. Pavanello et al. report on
new developments that overcome the experimental and theoretical difficulties that occur
beyond the barrier to linearity and largely unveil the elusive, highly excited H3+
spectrum.
Experimentally, at the MPI for Nuclear Physics,
the sensitivity of ion trap spectroscopy on H3+ has been increased,
which now allows to measure the frequencies of ro-vib transitions extending
far into the visible spectral range.
The new, precisely measured overtone frequencies gave decisive hints to an international
group of molecular theorists on how to dramatically improve their first-principles
quantum calculations of this fundamental triatomic molecule. They could obtain
a model which reproduces the new observations precisely and is capable of describing the full
ro-vib spectrum of H3+.
The described work provides the most accurate global ground-state H3+ potential energy
surface (PES) available to date. Together with a simple model for nonadiabatic effects,
it is now able to predict the ro-vib transitions of H3+ with unprecedented accuracy.
Please read more in the article ... >
Detailed information also in the press release of the MPIK
and the IDW
Although at first sight it seems very unlikely, negatively charged hydrogen molecules (H2– ions) can be metastable with a lifetime of a few microseconds. Experiments of the group "Molecular quantum dynamics and stored ion beams" of Andreas Wolf showed how hydrogen molecules can hold on to an extra electron for several microseconds. These molecule ions are rapidly rotating, they are very large and are finally decaying into neutral hydrogen molecules. The experimental results have just been published in Physical Review Letters. They confirm theoretical predictions.
Please read more in the article ... >
Detailed information also in the press release of the MPIK
and
the reports of APS Physics
and
Physics Today
.
The time-of-flight (TOF) ion-cyclotron-resonance (ICR) technique for the mass determination
of short-lived nuclides has recently been improved by the replacement of the
quadrupolar excitation by an octupolar excitation of the ion motion. In a just in Physical Review
Letters published article S. Eliseev et al. present the first analytical description of this
novel octupolar technique and report on its application for a direct Penning-trap
mass-ratio determination of the 164Er-164Dy mass doublet.
The new technique provided an increase in
resolving power by more than an order of magnitude and, thus, allowed a simultaneous measurement of
the cyclotron frequencies of 164Dy+ and 164Er+.
164Er is a promising candidate for a search for
neutrinoless double-electron capture. An observation of this neutrinoless transition would prove
that the neutrino is a Majorana particle. The measured Qee value of 25.07(12) keV for 164Er
results in a half-life of 1030 years for a 1 eV mass of a Majorana neutrino.
Please read more in the article ... >



